范勇;蒋国盛;张凌;宁伏龙;胡代平;陆洪智;刘力;韩博;

• 1:中国地质大学岩土钻掘与防护教育部工程研究中心
• 2:中国地质大学研究生院
• 3:福建省建筑科学研究院结构检测所
• 4:中国地质大学工程学院

摘要(Abstract)：

热开采法、抑制剂刺激法等传统天然气水合物开采方法将破坏水合物地层,不能有效地解决海底地层破坏和开采使用化石燃料燃烧后所存在的碳储存和碳捕捉问题。介绍了低温固体氧化物燃料电池法开采天然气水合物的方法。该方法利用CO2置换天然气水合物地层中的甲烷,运送到低温固体氧化物燃料电池的阳极,在阴极通入空气,发生电化学反应,产生电能,并将产出的CO2通入到天然气水合物地层,置换出甲烷。该方法简单、实用,克服了传统开采方法所存在的问题,发电效率较传统发电方法大幅提高。

关键词(KeyWords)： 天然气水合物;开采;低温固体氧化物燃料电池;二氧化碳;海底;冻土水合物;发电

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金项目(50704028;50904053);; 中国地质大学(武汉)中央高校基本科研业务费专项资金项目(CUGL090217);中国地质大学(北京)科学钻探国家专业实验室开放课题(NLSD200901)

作者(Author): 范勇;蒋国盛;张凌;宁伏龙;胡代平;陆洪智;刘力;韩博;

Email:

DOI:

参考文献(References)：

• [1]Collett T S,Kuuskraa V A.Hydrates contain vast store ofworld gas resources[J].Oil&Gas Journal,1998,96(11):90-95.
• [2]Milkov A V.Global estimates of hydrate-bound gas in marinesediments:How much is really out there[J].Earth Science Re-views,2004,66(3/4):183-197.
• [3]Darvish M P.Gas production from hydrate reservoir sand itsmodeling[J].Journal of Petroleum Technology,2004,56:65-71.
• [4]李燕,诸林,朱天阁,等.促进天然气水合物生成的研究进展[J].西南石油大学学报,2007,29(增刊1):46-49.
• [5]Kamath V A.A perspective on gas production from hydrate[C]∥Anon.Paper Presented at the JNOC′s Methane HydrateIntl.Symposium,Japan.[S.l.]:[s.n.],1998:87-92.
• [6]汤凤林,蒋国盛,K EБасниев,等.利用双井筒大水平距对接井钻井技术热力开采天然气水合物[J].探矿工程,2010,37(3):1-4.
• [7]Numasawa M,Dallimore S R,Yamamoto K,et al.Objectivesand operation overview of the JOGMEC/NrCan/Aurora MAL-LIK gas hydrate production test[C]∥Anon.Proceedings of the6th International Conference on Gas Hydrates(ICGH 2008).Vancouver,British Columbia,Canada:[s.n.],2008.
• [8]Yosuke M,Masahiro M,Gen I,et al.Study of recovery sys-tem of methane hydrate using gas lift method[C]∥Anon.Pro-ceedings of the 6th International Conference on Gas Hydrates.Vancouver,British Columbia,Canada:[s.n.],2008.
• [9]Glasby G P.Potential impact on climate of exploitation ofmethane hydrate deposits offshore[J].Marine and PetroleumGeology,2003(20):163-175.
• [10]Sivaraman R.The potential role of hydrate technology in se-questering carbon dioxide[EB/OL].Gas Tips.Fall 2003.http:∥www.gastechnology.org/.
• [11]Ebinuma T.Method for dumping and disposing of carbon diox-ide gas and apparatus therefore[P].U.S.Patent,1993,5261490.
• [12]Anderson R,Liamedo M,Tohidi B,et al.Experimentalmesurement of methane and carbon dioxide Clathrate hydrateequilibria in mesoporous silica[J].Phys.Chem.B.,2003,107:3507-3514.
• [13]Akihiro H.Phase equilibriumand comparison of formationspeeds of CH4and CO2hydrate below the ice point[C]∥A-non.Proceedings of tshe fifth International Conference on GasHydrates,Norway.Norway:[s.n.],2005.
• [14]Ohgaki K,Takano K,Sangawa H,et al.Methane exploita-tion by carbon dioxide from gas hydrates-phase equilibria forCO2-CH4mixed hydrate system[J].Chem.Eng.Jpn.,1996,29(3):478-483.
• [15]Seo Y,Lee H.Multiple-phase hydrate equilibria of the ternarycarbon dioxide,methane and water[J].J.Phys.Chem.:B,2001,105:10084-10090.
• [16]Masaki O,Kenji M,Yuki A,et al.Replacement of CH4in thehydrate by use of liquid CO2[J].Energy Conversion and Man-agemen,2005,46:1680-1691.
• [17]毛宗强.电源技术低温固体氧化物燃料电池研究进展[J].电源技术,2008,32(2):75-79.
• [18]黄建兵,杨立寨,彭冉冉,等.新型低温固体氧化物燃料电池研究进展[J].太阳能学报,2005,26(1):134-140.
• [19]Williams M C,Singhal S C.Mass produced ceramic fuel cellsfor low-cost power[J].Fuel Cells Bulletin,2000(24):8-11.
• [20]Suzuki T,Funahashi Y,Yamaguchi T,et al.Fabrication andcharacterization of micro tubular SOFC for advanced ceramicreactors[J].Journal of Alloys and Compounds,2007(4):149-156.
• [21]Suzuki T,Funahashi Y,Yamaguchi T,et al.Anode-supportedmicro tubular SOFCs for advanced ceramic reactor system[J].Journal of Power Sources,2007,171(1):92-95.
• [22]Suzuki T,Funahashi Y,Yamaguchi T,et al.Design and fabri-cation of light weight submillimeter tubular solid oxide fuelcells[J].Electrochemical and Solid-State Letters,2007,10(8):177-179.
• [23]Zhu B.Executive summary[EB/OL].[2007-01-01].http:∥www.gett.se/?id=1.
• [24]梁广川.燃料电池中温固体电解质材料研究[D].天津:天津大学,2000:12-13.
• [25]李遵照,郭绪强,陈光进,等.CO2置换CH4水合物中CH4的实验和动力学[J].化工学报,2007,58(5):1197-1203.
• [26]安连锁,张健,刘树华,等.固体氧化物燃料电池与燃气轮机混合发电系统[J].可再生能源,2008,26(1):62-64.
• [27]McGrail B P,Zhu T,Hunter R B,et al.A new method forenhanced production of gas hydrates with CO2[C]∥Anon.AAPG Hedberg Conference,Vancouver,[s.n.],2004:12-16.
• [28]White M D,Wurstner S K,McGrail B P,et al.Numericalstudies of methane production from Class 1gas hydrate accu-mulations enhanced with carbon dioxide injection[J].Marineand Petroleum Geology,2010,28(2):546-560.
• [29]Dicks A L.Hydrogen generation from natural gas for the fuelcell systems of tomorrow[J].Journal of Power Sources,1996,61(1/2):113-124.
• [30]Park S,Gorte R J,Vohs J M.Applications of heterogeneouscatalysis in the direct oxidation of hydrocarbons in a solid-oxidefuel cell[J].Applied Catalysis A:General,2000,200(1):55-61.
• [31]电气学会,燃料电池发电21世纪系统技术调查专门委员会.燃料电池技术[M].谢晓峰,范星河,译.北京:化学工业出版社,2004.
• [32]李瑛.燃料电池[M].北京:冶金工业出版社,2000.