邱啸飞;凌文黎;

• 1:中国地质大学地质过程与矿产资源国家重点实验室
• 2:中国地质大学地球科学学院
• 3:中国地质大学研究生院

摘要(Abstract)：

应用激光剥蚀—多接收器电感耦合等离子体质谱(LA-MC-ICP-MS)和二次离子质谱(SIMS)等分析技术进行微区原位普通Pb同位素分析是微区地球化学研究的重要内容之一。综述了矿物、熔体包裹体和沉积结核的微区原位普通Pb同位素分析技术及其地质应用的新进展。这些研究资料表明该分析技术在岩浆岩成因、沉积物物源示踪、地幔地球化学、古海洋学以及矿床学等的研究中提供了常规的全岩Pb同位素分析方法难以获得的重要信息,充分展示了该分析技术在地球科学研究中的应用前景。

关键词(KeyWords)： 微区原位分析;普通铅同位素;地质应用

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金委员会创新研究群体基金项目(40821061);; 教育部和国家外国专家局高等学校学科创新引智计划项目(B07039);; 国家自然科学基金面上项目(4067302540873017)

作者(Author): 邱啸飞;凌文黎;

Email:

DOI:

参考文献(References)：

• [1]Fryer D,Jackson S,Longerich H.The application of laser ab-lation microprobe-inductively couple plasma mass spectrometry(LAM-ICP-MS)toin situ(U)-Pb geochronology[J].Chemi-cal Geology,1993,109:1-8.
• [2]Hirata T,Nesbitt R W.U-Pb isotope geochronology of zir-con:Evaluation of the laser probe inductively coupled plasmamass spectrometry technique[J].Geochi micaet Cosmochi micaActa,1995,59:2 491-2 500.
• [3]Jackson S E,Pearson NJ,Griffin WL,et al.The applicationof laser ablationinductively coupled plasma-mass spectrometryto in situ U-Pb zircon geochronology[J].Chemical Geology,2004,211:47-69.
• [4]Willigers B J A,Baker J A,Krogstad E J,et al.Precise andaccurate in situ Pb-Pb dating of apatite,monazite and spheneby laser ablation multiple-collector ICP-MS[J].Geochi mica etCosmochi mica Acta,2002,66:1 051-1 066.
• [5]毕诗健,李建威,赵新福.热液锆石U-Pb定年与石英脉型金矿成矿时代:评述与展望[J].地质科技情报,2008,27(1):69-76.
• [6]Griffin WL,Belousova E A,Shee S R,et al.Archean crustalevolution inthe northern Yilgarn Craton:U-Pb and Hf-isotopeevidence from detrital zircons[J].Precambrian Research,2004,131:231-282.
• [7]Condie K C,Beyer E,Belousova E A,et al.U-Pbisotopic a-ges and Hf isotopic composition of single zircons:The searchfor juvenile Precambrian continental crust[J].PrecambrianResearch,2005,139:42-100.
• [8]Hawkesworth C J,Kemp AI S.Using hafnium and oxygenisotopes in zircons to unravel the record of crustal evolution[J].Chemical Geology,2006,226:144-162.
• [9]钟玉芳,马昌前,佘振兵.锆石地球化学特征及地质应用研究综述[J].地质科技情报,2006,25(1):27-34.
• [10]Andersen C A,Hinthorne J R.U,Th,Pb and REE abun-dances and207Pb/206Pb ages of individual minerals in returnedlunar material by ion microprobe mass analysis[J].Earth andPlanetary Science Letters,1972,14:195-200.
• [11]Brevard O,Shi mizu N,Allegre CJ.Intra-andinter-crystallinevariation of Pbisotopic compositionin galena fromthe Missis-sippi Valley type ores:Anion microprobe study[R].[S.l.]:USGS open-file report,1978.
• [12]Shi muzu N,Semet M P,Allegre C J.Geochemical applica-tions of quantitativeion-microprobe analysis[J].Geochi micaetCosmochi mica Acta,1978,42:1 321-1 334.
• [13]Compston W,Williams I S,Meyer C.U-Pb geochronology ofzircons from Lunar Braccia 73217 using sensitive high-resolu-tion ion microprobe[J].Journal of Geophysical Research,1984,89(Supplementary):525-534.
• [14]Blake L P,Willians I S,Compston W.Four zircon ages fromone rock:The history of a 3 930 Ma old granulite from MountStones,Enderby Land,Antarctica[J].Contribution to Min-eralogy and Petrology,1986,94:427.
• [15]Hart S R,Shi mizu N.Lead isotope zoning in galena:An ionmicroprobe study of a galena crystal from the Buick Mine,Southeast Missouri[J].Economic Geology,1981,76:1 873-1 878.
• [16]Saal A E,Hart S R,Shi mizu N,et al.Pb isotopic variabilityin melt inclusions from oceanic island basalts,Polynesia[J].Science,1998,282:1 481-1 484.
• [17]Walder AJ,Freedman P A.Isotopic ratio measurement usinga double focusing magnetic sector mass analyzer with aninduc-tively coupled plasma as anion source[J].Journal of Analyti-cal Atomic Spectrometry,1992,7:571-575.
• [18]Christensen J N,Halliday A N,Godfrey L V,et al.Cli mateand ocean dynamics and the leadisotopic records in Pacific fer-ro-manganese crusts[J].Science,1997,277:913-918.
• [19]Sie S H,Niklaus T R,Suter G F,et al.Microbeam AMS:Prospects of new geological applications[J].Nuclear Instru-ments and Methods in Physics Research B,1997,123:112-121.
• [20]Sie S H,Si ms D A,Suter G F,et al.Precision Pb and Siso-topic ratio measurements by microbeam AMS[J].Nuclear In-struments and Methods in Physics Research B,2000,172:228-234.
• [21]Sie S H,Niklaus T R,Si ms D A,et al.AUSTRALIS:Anewtool for the study of isotopic systems and geochronology inmineral systems[J].Australian Journal of Earth Sciences,2002,49:601-611.
• [22]Jochum K P,Stoll B,Herwig K,et al.Lead isotope ratiomeasurements in geological glasses by laser ablation-sectorfield-ICP mass spectrometry(LA-SF-ICPMS)[J].Internation-al Journal of Mass Spectrometry,2005,242:281-289.
• [23]靳兰兰,姜劲峰,胡圣虹,等.双气流路-激光剥蚀电感耦合等离子体质谱测定铅同位素比值[J].分析化学,2007,35(2):191-195.
• [24]Meffre S,Large R R,Scott R,et al.Age and pyrite Pb-iso-tope composition of the giant Sukhoi Log sedi ment-hosted golddeposit,Russia[J].Geochi micaet Cosmochi mica Acta,2008,72:2 377-2 391.
• [25]Woodhead J,Hergt J,Meffre S,et al.In situ Pb-isotope anal-ysis of pyrite bylaser ablation(multi-collector and quadrupole)ICPMS[J].Chemical Geology,2009,262:344-354.
• [26]Kobayashi K,Tanaka R,Moriguti T,et al.Lithium,boron,and leadisotope systematics of glassinclusionsin olivines fromHawaiian lavas:Evidence for recycled components in the Ha-waiian plume[J].Chemical Geology,2004,212:143-161.
• [27]Jochum K P,Stoll B,Herwig K.I mprovedin situ Pb isotopeanalysis of low Pb samples by LA-ICP-MS using a solid-state193 nm Nd:YAGlaser[C]∥Geochi ma et Cosmochi ma Acta.Goldschmidt Conference Abstracts.[S.l.]:[s.n.],2006:A294.
• [28]Baker J,Waight T E,Meyzen C.Pbisotopic analysis of stand-ards and samples using a207Pb-204Pb double spike and thalliumto correct for mass bias with a double focusing MC-ICP-MS[J].Chemical Geology,2004,211:275-303.
• [29]Tyrrell S,Haughton P D W,Daly J S,et al.The use of thecommon Pbisotope composition of detrital K-feldspar grains asa provenance tool and its application to Upper Carboniferouspaleodrainage,northern England[J].Journal of Sedi mentaryResearch,2006,76:324-345.
• [30]胡圣虹,杨薇,帅琴,等.电感耦合等离子体质谱测定地质样品中Pb同位素比值[J].高等学校化学学报,2003,24(1):55-57.
• [31]Saal A E,Hart S R,Shi mizu N,et al.Pb isotopic variabilityin melt inclusions from the EMI-EMII-HI MU mantle end-members andthe role of the oceaniclithosphere[J].EarthandPlanetary Science Letters,2005,240:605-620.
• [32]Gragnevin D,Daly J S,Waight T E,et al.Pbisotopic zoningof K-feldspar megacrysts determined by Laser Ablation Multi-Collector ICP-MS:Insights into granite petrogenesis[J].Geochi micaet Cosmochi mica Acta,2005,69:1 899-1 915.
• [33]Zart man R E,Haines S M.The plumbotectonic model for Pbisotopic systematic among major terrestrial reservoirs-a casefor bidirectional transport[J].Geochi maet Cosmochi ma Acta,1988,52:1 327-1 339.
• [34]Wolff J A,Ramos F C.Pb isotope variations among BandelierTuff feldspars:No evidence for a long-lived silicic magmachamber[J].Geology,2003,31:533-536.
• [35]Mathez E A,Waight T.Lead isotopic disequilibrium betweensulfide and plagioclaseinthe Bushveld Complex andthe chemi-cal evolution of large layeredintrusion[J].Geochi micaet Cos-mochi mica Acta,2003,67:1 875-1 888.
• [36]Tyrrell S,Haughton P D W,Daly J S,et al.Drainage reor-ganization during breakup of Pangea revealed by in-situ Pbisotopic analysis of detrital K-feldspar[J].Geology,2007,35:971-974.
• [37]Tyrrell S,Haughton P D W,Daly J S,et al.Paleodrainagereconstruction using Pb isotopes in K-feldspar sand grains:Examples fromthe NWEuropean Triassic[C]∥Geochi mica etCosmochi mica Acta.Goldschmidt Conference Abstracts.[S.l.]:[s.n.],2008:963.
• [38]Zindler A,Hart S R.Chemical geodynamics[J].Annual Re-viewofthe Earth and Planetary Sciences,1986,14:493-571.
• [39]Hof mann A W.Mantle geochemistry:The message fromoce-anic volcanism[J].Nature,1997,385:219-229.
• [40]Hauri E H,Hart S R.Re-Os isotope systematics of HI MUand EMII oceanic island basalts fromthe South Pacific Ocean[J].Earth and Planetary Science Letters,1993,114:353-371.
• [41]Yuri moto H,Kogiso T,Abea K,et al.Leadisotopic compo-sitions in olivine-hosted melt inclusions from HI MU basaltsand possible link to sulfide components[J].Physics of theEarth and Planetary Interiors,2004,146:231-242.
• [42]Cochran J K,McKibbin V T,Dornblaser M M,et al.210Pbscavengingin the North Atlantic and North Pacific oceans[J].Earth and Planetary Science Letters,1990,97:332-352.
• [43]Peate D W,Falkena L,Kent AJ R.Pb isotope variations inhydrogenetic Fe-Mn crusts from the Izu-Bonin fore-arc[J].Chemical Geology,2009,258:288-298.
• [44]Kent AJ R,Dilles J H.In-situ analysis of Pbisotope ratios byLA-MC-ICP-MS:Applications to ore genesis and igneouspetrogenesis[C]∥Geochi mica et Cosmochi mica Acta.Gold-schmidt Conference Abstracts.[S.l.]:[s.n.],2005:A376.